Narrated by Abdullah ibn Amr ibn al-'As (RA): A man said: O Messenger of Allah, the mu'adhdhins excel us. The Messenger of Allah (ﷺ) said: Say (the same words) as they say, and when you come to the end, ask Allah for anything and that will be granted to you.
Anas (RA) said, the Prophet (ﷺ) said, when the call to prayer (adhan) is given, the gates of heaven are opened and the dua is accepted.
Allah (SWT) says -
إِنَّا أَنزَلْنَاهُ فِي لَيْلَةِ الْقَدْرِ ﴿١﴾ وَمَا أَدْرَاكَ مَا لَيْلَةُ الْقَدْرِ ﴿٢﴾ لَيْلَةُ الْقَدْرِ خَيْرٌ مِّنْ أَلْفِ شَهْرٍ ﴿٣﴾ تَنَزَّلُ الْمَلَائِكَةُ وَالرُّوحُ فِيهَا بِإِذْنِ رَبِّهِم مِّن كُلِّ أَمْرٍ ﴿٤﴾ سَلَامٌ هِيَ حَتَّىٰ مَطْلَعِ الْفَجْرِ ﴿٥﴾
اِنَّا اَنْزَلْنَاهُ فِيْ لَيْلَةِ الْقَدْرِ ﴿١﴾ وَمَا اَدْرَاكَ مَا لَيْلَةُ الْقَدْرِ ﴿٢﴾ لَيْلَةُ الْقَدْرِ خَيْرٌ مِّنْ اَلْفِ شَهْرٍ ﴿٣﴾ تَنَزَّلُ الْمَلَائِكَةُ وَالرُّوْحُ فِيْهَا بِاِذْنِ رَبِّهِمْ مِّن كُلِّ اَمْرٍ ﴿٤﴾ سَلَامٌ هِيَ حَتّٰي مَطْلَعِ الْفَجْرِ ﴿٥﴾
(1) Indeed, We sent the Qur'an down during the Night of Decree. (2) And what can make you know what is the Night of Decree? (3) The Night of Decree is better than a thousand months. (4) The angels and the Spirit descend therein by permission of their Lord for every matter. (5) Peace it is until the emergence of dawn.
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